In the spirit of the Superfund Basic Research Program’s
(SBRP’s) mandate to develop mechanisms to deliver research
findings to interested stakeholders, CROET and the SBRC recently
sponsored a one-day scientific symposium entitled Trichloroethylene
(TCE) from the ground up: Contaminated sites, health effects,
and remediation strategies. The Symposium was held on May
21, 2004 in downtown Portland. The purpose of the symposium was
to bring together experts from academia and government with the
goal of understanding TCE’s impact in the region. Speakers
represented both government agencies and academic institutions.
Represented government agencies were EPA Region 10, Oregon Department
of Environmental Quality, and Oregon Department of Human Services,
while academic speakers were affiliated with Oregon Health &
Science University/CROET, Oregon State University, and Washington
State University. The symposium provided an ideal opportunity
to bring together a diverse group of people who addressed Superfund
issues from a variety of perspectives.
TCE is a nonflammable, colorless liquid that is used mainly
as a solvent to remove grease from metal parts, but it is also
an ingredient in adhesives, paint removers, typewriter correction
fluids, and spot removers. TCE is not thought to occur naturally
in the environment. However, it has been found in underground
water sources and many surface waters as a result of its manufacture,
use, and disposal (ATSDR, 1997). TCE is an important Superfund
site contaminant, an important regional and national contaminant,
and a key contaminant of concern in our SBRC. The specific focus
of our SBRC is Superfund chemicals that produce neurotoxic effects,
and TCE and several of its breakdown products are known to be
neurotoxic (ATSDR, 1997). In addition, there is great public interest
in the issue of TCE groundwater contamination at the former local
View Master plant, a manufacturing plant that government agencies
are involved in cleaning up.
TCE Contamination at RCRA and Superfund Sites in
the Northwest: Howard Orlean, U.S. Environmental Protection Agency,
Region 10. Mr. Orlean is the Corrective Action Coordinator
for the RCRA (Resource Conservation and Recovery Act) Program
at EPA Region 10. There are 23 Superfund sites in Washington and
Oregon with TCE contamination. At all of these sites, TCE contamination
is found in groundwater. Concentrations vary from below drinking
water standards (5 parts per billion, ppb) up to 1000-2000 ppb.
EPA is addressing this health risk by cleaning up sites to groundwater
standards. Mr. Orlean subsequently illustrated this by detailing
the risk management strategy for the Philip Services Corporation
Georgetown facility in Seattle.
Oregon Environmental Cleanup Program: TCE Cleanup
Approaches and Issues: Bruce Gilles, Oregon Department of Environmental
Quality (DEQ). Mr. Gilles is a project manager with
the Oregon DEQ’s Cleanup. Over the course of his career
he has managed a number of investigation and cleanup projects
throughout Oregon involving chlorinated solvents, and his talk
presented the criteria and methods he uses to evaluate, investigate,
and remediate TCE-contaminated sites. One case study of particular
public interest involved the local former View Master plant, where
TCE had been used for 30 years, and which now has extremely high
levels of TCE in its former drinking water wells. The area has
shallow groundwater contamination and high TCE levels in a deep
basalt aquifer. DEQ’s risk assessment determined that there
was an unacceptable risk to on-site and utility workers, as well
as from future use of groundwater. Treatment has begun using chemical
oxidation, air stripping, and carbon filtration. The cleanup will
take 30 years.
TCE: Public Health Perspective: David Stone & Michael
Heumann, Oregon Department of Human Services (DHS).
Dr. Stone is a public health toxicologist who examines the public
health implications of exposure to environmental contaminants.
Mr. Heumann is an epidemiologist whose primary area of focus is
occupational and environmental epidemiology. Together, they presented
case studies involving TCE from a public health perspective. Mr.
Heumann spoke about the View Master plant, a local former manufacturing
plant that is now highly contaminated with TCE. TCE contamination
was first found in the plant's drinking water well in 1998. DEQ
has estimated that the well had been contaminated for over 20
years, resulting in a large number of workers exposed to TCE in
the drinking water. The proposed public health response plan included
recreating the cohort, designing public health outcome studies,
and conducting dose and exposure reconstruction analysis. The
first step was to review mortality data from Oregon and the US.
Conclusions thus far indicate that the well contamination constitutes
a past public health hazard, with proportional excesses of kidney
and pancreatic cancer, and that a more thorough investigation
of the impact of these data on the local community is needed.
Health Effects of TCE: Richard Bull, Washington State
University. Dr. Bull, a retired toxicology professor,
presented studies that primarily focused on the carcinogenic properties
of TCE. There is data indicating that TCE causes kidney, liver,
esophageal, and cervical cancer, as well as non-Hodgkin’s
lymphoma, in humans. He also described several studies of TCE-induced
liver cancer in mice.
Methods for Determining In-Situ Rates of Reductive
Dechlorination in Groundwater: Jennifer Field, Oregon State University
& Superfund Basic Research Center. Dr. Field
is a professor of environmental and molecular toxicology who spoke
about her SBRC-sponsored research. She stated that in-situ rate
determining methods are necessary in order to assess the potential
for intrinsic bioremediation, to design engineered bioremediation
projects, and to monitor remediation progress. However, these
rates can be difficult to obtain. Her research involves modifying
the “push-pull” test, in which a prepared test solution
containing tracer and a substrate is injected into a monitoring
well and then samples are collected and analyzed for tracer, substrate,
and product. Conclusions from these studies stated that using
TCFE to measure in-situ reductive dechlorination rates is a cost-effective,
simple method to obtain rate information, and can be effectively
applied in the field.
Anaerobic Biological Processes and Abiotic Remediation:
Lewis Semprini, Oregon State University & Superfund Basic
Research Center. Dr. Semprini, professor of civil,
construction, and environmental engineering, spoke about his research
on biological processes for the treatment of hazardous wastes,
and on the fate and transport of organic contaminants in the environment.
He specializes in field, laboratory, and modeling studies. He
spoke about his work identifying microorganisms that reductively
dechlorinate TCE, using molecular biology techniques to identify
bacteria and modeling studies to determine reductive dechlorination
rates of TCE.